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The following are locations of various programs in the Windows 10 System32 folder. You can create shortcuts to these on your Microsoft Windows 10 computer rather than trying to figure out how to access them with the Windows 10 start menu. Some I am sure you can't access that way. There are other programs not listed here that are in the System 32 folder that will only run from a command line.
%SystemRoot%
default location: C:\Windows
---
Accessibility On-Screen Keyboard
%SystemRoot%\System32\osk.exe
Add Hardware Wizard
%SystemRoot%\System32\hdwwiz.exe
Advanced System Settings
%SystemRoot%\System32\SystemPropertiesAdvanced.exe
Advanced User Accounts Control Panel
%SystemRoot%\System32\Netplwiz.exe
Bluetooth File Transfer
%SystemRoot%\System32\fsquirt.exe
Change Computer Performance Settings
%SystemRoot%\System32\SystemPropertiesPerformance.exe
Change Computer Settings (General Tab)
%SystemRoot%\System32\SystemPropertiesComputerName.exe
Change Data Execution Prevention Settings
%SystemRoot%\System32\SystemPropertiesDataExecutionPrevention.exe
Character Map
%SystemRoot%\System32\charmap.exe
ClearType Tuner
%SystemRoot%\System32\cttune.exe
Computer Management Snapin Launcher
%SystemRoot%\System32\CompMgmtLauncher.exe
Create a shared folder wizard
%SystemRoot%\System32\shrpubw.exe
Create Recovery Drive
%SystemRoot%\System32\RecoveryDrive.exe
Create Windows Repair Disk
%SystemRoot%\System32\recdisc.exe
Credential Backup and Restore Wizard
%SystemRoot%\System32\credwiz.exe
Device Pairing Wizard
%SystemRoot%\System32\DevicePairingWizard.exe
Diagnostics Troubleshooting Wizard
%SystemRoot%\System32\msdt.exe
DirextX Diagnostic Tool
%SystemRoot%\System32\dxdiag.exe
Disk Cleanup
%SystemRoot%\System32\cleanmgr.exe
Display Color Calibration
%SystemRoot%\System32\dccw.exe
DPI Scaling
%SystemRoot%\System32\DpiScaling.exe
Driver Verifier Manager
%SystemRoot%\System32\verifiergui.exe
or
%SystemRoot%\System32\verifierg.exe
DVD Media player
%SystemRoot%\System32\dvdplay.exe
Event Viewer Snapin Launcher
%SystemRoot%\System32\eventvwr.exe
Features On Demand Helper (Fonts)
%SystemRoot%\System32\fodhelper.exe
File History
%SystemRoot%\System32\FileHistory.exe
File Signature Verification
%SystemRoot%\System32\sigverif.exe
Icons for shortcuts
%SystemRoot%\system32\SHELL32.dll
%SystemRoot%\system32\imageres.dll
You can also use icons from any program file that has one
IExpress 2.0 (Create self extracting self-installing package)
%SystemRoot%\System32\iexpress.exe
Language Pack Installer
%SystemRoot%\System32\lpksetup.exe
LDP
%SystemRoot%\System32\ldp.exe
Malicious Software Removal Tool
C:\Windows\System32\MRT.exe
Manage Work Folders
%SystemRoot%\System32\WorkFolders.exe
Manage your file encriyption certificates
%SystemRoot%\System32\rekeywiz.exe
Master Control Panel
Create a folder and label it:
MasterControl.{ED7BA470-8E54-465E-825C-99712043E01C}
(‘MasterControl’ can be replaced with any lablel)
Memory Diagnostics Tool
%windir%\system32\MdSched.exe
Microsoft Color Control Panel
%SystemRoot%\System32\colorcpl.exe
Microsoft Fax Cover Page Editor
%SystemRoot%\System32\FXSCOVER.exe
Microsoft iSCSI Initiator Configuration Tool
%SystemRoot%\System32\iscsicpl.exe
Microsoft Management Console
%SystemRoot%\System32\mmc.exe
Microsoft Screen Magnifier
%SystemRoot%\System32\Magnify.exe
Microsoft Sync Center
%SystemRoot%\System32\mobsync.exe
Microsoft Telnet Client
%SystemRoot%\System32\telnet.exe
Microsoft Windows Malicious Software Removal Tool
%SystemRoot%\System32\MRT.exe
Microsoft Windows Phone Dialer
%SystemRoot%\System32\dialer.exe
Microsoft® Drive Optimizer
%SystemRoot%\System32\dfrgui.exe
Microsoft® Windows Backup
%SystemRoot%\System32\sdclt.exe
Microsoft® Windows System Restore
%SystemRoot%\System32\rstrui.exe
ODBC Data Source Administrator
%SystemRoot%\System32\odbcad32.exe
Paint
%SystemRoot%\System32\mspaint.exe
Printer Migration Utility
%SystemRoot%\System32\PrintBrmUi.exe
Private Character Editor
%SystemRoot%\System32\eudcedit.exe
Registry Editor
%SystemRoot%\System32\regedt32.exe
or
%SystemRoot%\System32\regedt.exe
Remote Desktop Connection
%SystemRoot%\System32\mstsc.exe
Resource and Performance Monitor
%SystemRoot%\System32\perfmon.exe
Resource Monitor
%SystemRoot%\System32\resmon.exe
Screen Reader
%SystemRoot%\System32\Narrator.exe
Set Program Access and Computer Defaults Control
%SystemRoot%\System32\ComputerDefaults.exe
SmartScreenSettings
%SystemRoot%\System32\SmartScreenSettings.exe
SQL Client Configuration Utility EXE
%SystemRoot%\System32\cliconfg.exe
Steps Recorder(Record all the actions you take. Records screen shots.)
%SystemRoot%\System32\psr.exe
Sticky Notes
%SystemRoot%\System32\StikyNot.exe
System Configuration Utility
%SystemRoot%\System32\msconfig.exe
System Information
%SystemRoot%\System32\msinfo32.exe
System Properties (Hardware Settings)
%SystemRoot%\System32\SystemPropertiesHardware.exe
System Protection Settings
%SystemRoot%\System32\SystemPropertiesProtection.exe
System Remote Settings
%SystemRoot%\System32\SystemPropertiesRemote.exe
System Reset for Windows
%SystemRoot%\System32\systemreset.exe
Task Manager Launcher
%SystemRoot%\System32\LaunchTM.exe
User Account Control Settings
%SystemRoot%\System32\UserAccountControlSettings.exe
Userinit Logon Application (Opens Windows Explorer)
%SystemRoot%\System32\userinit.exe
Utility Manager
%SystemRoot%\System32\Utilman.exe
Voice Recorder
(Enter 'Voice Recorder' in the start menu)
Volume Mixer
%SystemRoot%\System32\SndVol.exe
whoami - displays logged on user information
%SystemRoot%\System32\whoami.exe
Windows Activation Client (Change Product Key)
%SystemRoot%\System32\slui.exe
Windows Control Panel
%SystemRoot%\System32\control.exe
Windows Fax and Scan
%SystemRoot%\System32\WFS.exe
Windows Features (Optional Programs)
%SystemRoot%\System32\OptionalFeatures.exe
Windows Memory Diagnostics Tool
%SystemRoot%\System32\MdSched.exe
Windows Mobility Center (only works on Laptops)
%SystemRoot%\System32\mblctr.exe
Windows Picture Acquisition Wizard
%SystemRoot%\System32\wiaacmgr.exe
Windows Remote Assistance
%SystemRoot%\System32\msra.exe
Wordpad
%SystemRoot%\System32\write.exe
XPS Viewer
%SystemRoot%\System32\xpsrchvw.exe